Precise determination of optical band gap in Cr-doped semiconductor nanowires

نویسندگان

چکیده

Pristine and chromium-doped ZnO nanowires were prepared following the traditional co-precipitation method. X-ray diffraction data identified a pure wurtzite hexagonal crystal structure characteristic for ZnO, irrespective of doping level. The particle size, as deduced form Williamson–Hall plots, was found to be 45–55 nm all samples. Scanning electron microscopy revealed clear morphology doped samples, while elemental analysis ensured successful Cr-doping. Distinct spectroscopic signatures Cr-doping from detailed deconvolution process applied optical spectra where Cr3+ transitions unambiguously at ~ 420 665 nm. Particularly relevant, is spectral decomposition here performed superimposed absorption edge (~ 385 nm) Cr3+ resonance nm, allowing claim practically doping-independent band gap behavior in present regime. This further supported by identifying near photoluminescence peak 392 which maintains fixed wavelength after These findings contrast earlier studies on Cr-doped semiconductor nanoparticles glass systems has been largely underestimated. We attribute inconsistence values reported literature semiconductors proximity Cr edge.

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ژورنال

عنوان ژورنال: Optical and Quantum Electronics

سال: 2022

ISSN: ['1572-817X', '0306-8919']

DOI: https://doi.org/10.1007/s11082-021-03462-1